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This shift introduces urgent challenges related to reliability, autonomy, accountability, and governance, particularly as such systems increasingly operate over personal and enterprise data. Personal Knowledge Graphs (PKGs) offer a promising foundation for addressing these issues by enabling explicit, machine-readable representations of context, policies, and provenance. Building on a successful Dagstuhl Seminar and prior TAPAI/TAAPAAI workshop editions at ISWC and ESWC, this workshop aims to consolidate and advance a growing research community focused on PKG-based agentic AI. The workshop will explore emerging architectures, decentralised ecosystems, and governance models for agentic systems grounded in semantic technologies. Adopting a Dagstuhl-style, discussion-led format, the workshop will emphasise collaborative exploration, cross-disciplinary exchange, and the co-creation of shared artefacts. 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